Reversible binding of hydrogencarbonate to a chiral di-aqua lanthanide complex occurs in the pH range 6.5–8.5, limiting the measured relaxivity in the gadolinium complex and enhancing the metal-based emission in the europium analogue.
S. Aime, A. Barge, M. Botta, J. A. K. Howard, R. Kataky, M. P. Lowe, J. M. Moloney, D. Parker and A. S. de Sousa, Chem. Commun., 1999, 1047 DOI: 10.1039/A902238D
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