1,1-Dihalo-1-lithio species (halogenocarbenoids) undergo double insertion into the carbon–zirconium bonds of a zirconacyclopent-ane or -ene to produce, after hydrolysis, bicyclo[3.3.0]oct-anes and -enes.
N. Vicart and R. J. Whitby, Chem. Commun., 1999, 1241 DOI: 10.1039/A901722D
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