Catalytic asymmetric aziridination of styrene by [N-(p-toluenesulfonyl)imino]phenyliodinane was achieved by manganese and iron tetramethylchiroporphyrins; opposite enantioselectivities were obtained with the two metal centers, and possible mechanisms are proposed to explain this unexpected result.
J. Simonato, J. Pécaut, J. Marchon and W. Robert Scheidt, Chem. Commun., 1999, 989 DOI: 10.1039/A901559K
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