Issue 8, 1999
From the journal:

Chemical Communications

Insertion of a metal-bound nitrogen atom into a disulfide (S–S) bond. Synthesis and characterisation of [CoIIIL2]ClO4 [HL = di(2-pyridylthio)amine]

Hiroaki Nakayama,   Keith Prout,   H. Allen O. Hill  and  Dipankar Datta  

Abstract

Reaction of cis-[CoIII(NH3)4(H2O)2](ClO4)3 with 2,2′-dithiodipyridine (2,2′-DTDP) in nearly equimolar proportion generates [CoIIIL2]ClO4 where HL (H = dissociable proton) is di(2-pyridylthio)amine, resulting in an unprecedented insertion of a coordinated ammine N into the S–S bond of 2,2′-DTDP.

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Article information

DOI
https://doi.org/10.1039/A901442J
Article type
Paper

Chem. Commun., 1999, 695-696

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Insertion of a metal-bound nitrogen atom into a disulfide (S–S) bond. Synthesis and characterisation of [CoIIIL2]ClO4 [HL = di(2-pyridylthio)amine]

H. Nakayama, K. Prout, H. Allen O. Hill and D. Datta, Chem. Commun., 1999, 695 DOI: 10.1039/A901442J

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