The complexation of alkali metal cations (Na+ and/or K+) by organic–inorganic hybrid materials incorporating dibenzo-18-crown-6 ether moieties covalently linked to silica by two Si–C bonds is explained in terms of deformations of the crown ether moiety during the sol–gel process
C. Chuit, R. J. P. Corriu, G. Dubois and C. Reyé, Chem. Commun., 1999, 723 DOI: 10.1039/A900767I
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