Issue 11, 1999

Metal–oxo cluster-supported transition metal complexes: hydrothermal synthesis and characterization of [{M(phen)2}2(Mo8O26)] (M = Ni or Co)

Abstract

Two new metal–oxo supported transition metal complexes, [{M(phen)2}2(Mo8O26) (M = Ni or Co; phen = 1,10-phenanthroline) are synthesized by a hydrothermal method and characterized by X-ray crystallography, showing that the octamolybdate possesses a novel unprecedented structure and that [M(phen)2]2+ units are covalently bonded to the [Mo8O26]4– cluster.

Article information

Article type
Paper

Chem. Commun., 1999, 983-984

Metal–oxo cluster-supported transition metal complexes: hydrothermal synthesis and characterization of [{M(phen)2}2(Mo8O26)] (M = Ni or Co)

J. Xu, R. Wang, G. Yang, Y. Xing, D. Li, J. Xu, W. Bu, L. Ye, Y. Fan, G. Yang, Y. Xing, Y. Lin and H. Jia, Chem. Commun., 1999, 983 DOI: 10.1039/A900643E

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