Two- and three-dimensional non-interpenetrating open-networks self- assembled by µ4-hexamethylenetetramine (hmt). Syntheses and structures of [Ag2(µ4-hmt)(SO4)(H2O)]·4H2O and [Ag2(µ4-hmt)(µ-O2CMe)]MeCO2·4.5H2O
Abstract
Sulfate and acetate complexes comprising two-dimensional grids with square cavities and three-dimensional networks with hexagonal channels, respectively, have been prepared and characterised by X-ray single-crystal structural analysis.