Absolute rate constants determined for 1,2-C and 1,2-H migrations of cyclobutyl-, cyclopentyl-, benzocyclobutenyl- and benzocyclopentenyl-(chloro)- or -(acetoxy)-carbenes reveal that ‘phenyl’ carbon migrations are preferred to alternative 1,2-C shifts due to π-electronic effects.
R. A. Moss, W. Ma and R. R. Sauers, Chem. Commun., 1999, 467 DOI: 10.1039/A809769K
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