Issue 4, 1999

‘Inverse crown ether’ complexes: extension to potassium through the synthesis of [{[(Me3Si)2N]4K2Mg2(O2)}], a peroxo-centred macrocycle linked into infinite chains by intermolecular K⋯CH3(SiMe2) interactions

Abstract

The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2– core.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 353-354

‘Inverse crown ether’ complexes: extension to potassium through the synthesis of [{[(Me3Si)2N]4K2Mg2(O2)}], a peroxo-centred macrocycle linked into infinite chains by intermolecular K⋯CH3(SiMe2) interactions

A. R. Kennedy, R. E. Mulvey, B. A. Roberts, R. B. Rowlings and C. L. Raston, Chem. Commun., 1999, 353 DOI: 10.1039/A809681C

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