Issue 5, 1999

A new synthetic path to peri-naphthisoxazoles by oxidative intramolecular cyclization of some β,γ-unsaturated oximes

Abstract

Some β,γ-unsaturated oximes undergo an unprecedented intramolecular cycloaddition to an aryl group to afford peri-naphthisoxazoles when they are irradiated in the presence of PhI(OAc)2 and I2 or HgO and I2 in benzene or by thermal reaction with NaOCl and Et3N in CH2Cl2.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 425-426

A new synthetic path to peri-naphthisoxazoles by oxidative intramolecular cyclization of some β,γ-unsaturated oximes

J. C. Barnes, W. M. Horspool and G. Hynd, Chem. Commun., 1999, 425 DOI: 10.1039/A809610D

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