SCHEDULED MAINTENANCE
Titanium-mediated diene metallabicyclisation–elimination–functionalisation has been utilised for the preparation of syn-3,4-disubstituted and syn,syn-2,3,4-trisubstituted pyrrolidines in high yield and excellent stereoselectivity; this methodology has been employed in a total synthesis of (–)-α-kainic acid starting from L-serine.
A. D. Campbell, R. J. K. Taylor and T. M. Raynham, Chem. Commun., 1999, 245 DOI: 10.1039/A809598A
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