Issue 4, 1999

Thiacalixarenes as cluster keepers: synthesis and structural analysis of a magnetically coupled tetracopper(II) square

Abstract

An X-ray structure determination of an antiferromagnetic copper complex of p-tert-butyltetrathiacalix[4]arene has shown it to contain a square, phenoxo- and sulfur-bridged cluster of four Cu(II) ions sandwiched between two fully deprotonated calixarenes, thus forming a ditopic, divergent receptor; as prepared, the complex has each cavity occupied by a molecule of dichloromethane.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 373-374

Thiacalixarenes as cluster keepers: synthesis and structural analysis of a magnetically coupled tetracopper(II) square

G. Mislin, E. Graf, M. Wais Hosseini, A. Bilyk, A. K. Hall, J. M. Harrowfield, B. W. Skelton and A. H. White, Chem. Commun., 1999, 373 DOI: 10.1039/A809184F

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