The exchange of carbonyls is a common feature for metal carbonyl compounds in solution whereas in the solid state high interatomic potential energy barriers cause this occurrence to be highly unlikely; it is shown that the compartmentalization of (arene)Cr(CO)3 in the β-cyclodextrin cavity removes any constraint and thereby facilitates the rotation of the Cr(CO)3 group in the solid state.
S. Aime, H. C. Canuto, R. Gobetto and F. Napolitano, Chem. Commun., 1999, 281 DOI: 10.1039/A809100E
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