Novel optically pure cholesteryl-phosphine ligands (3α-PPh2chol and 3β-PMe2chol) have been synthesized and were shown to form stable and highly soluble Pd(II) and Pt(II) complexes; as revealed by an X-ray analysis the (chol)P···P(chol) fragment of the square planar trans-[PtI2(3β-PMe2chol)2] complex adopts a staggered arrangement (V-shape).
D. Soulivong, D. Matt and R. Ziessel, Chem. Commun., 1999, 393 DOI: 10.1039/A809041F
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