Saddle shaped {2,3,6,8,11,12,15,17-octamethyldibenzo-[b,i]1,4,8,11-tetraaza(1,4)annulene}nickel(II), Ni(OMTAA),acts as a heterotropic divergent receptor molecule with C70 forming a 1:1 complex in the solid state, where the extended supramolecular array consists of zigzag alternating C70–Ni(OMTAA) chains and corrugated sheets of close contact C70 molecules.
P. D. Croucher, J. M. E. Marshall, P. J. Nichols and C. L. Raston, Chem. Commun., 1999, 193 DOI: 10.1039/A807990K
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