Issue 1, 1999
From the journal:

Chemical Communications

Synthesis and characterization of a new mixed-metal oxide framework material composed of vanadium oxide clusters: X-ray crystal structure of (N2H5)2[Zn3VIV12VV6O42(SO4)(H2O)12]·24H2O

M. Ishaque Khan,   Elizabeth Yohannes  and  Douglas Powell  

Abstract

The reaction of a slurry of V2O5 with LiOH·H2O and hydrazinium sulfate gives a dark colored solution that upon treatment with ZnSO4·7H2O yields the novel framework material (N2H5)2[Zn3VIV12VV6O42(SO4)(H2O)12]·24H2O, composed of three-dimensional arrays of the mixed-valence {V18O42(SO4)} clusters interlinked via {Zn(H2O)4} bridging groups, containing tunnels occupied by exchangeable cations and water molecules.

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Article information

DOI
https://doi.org/10.1039/A807503D
Article type
Paper

Chem. Commun., 1999, 23-24

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Synthesis and characterization of a new mixed-metal oxide framework material composed of vanadium oxide clusters: X-ray crystal structure of (N2H5)2[Zn3VIV12VV6O42(SO4)(H2O)12]·24H2O

M. Ishaque Khan, E. Yohannes and D. Powell, Chem. Commun., 1999, 23 DOI: 10.1039/A807503D

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