SCHEDULED MAINTENANCE
3-p-Tolyl-3-trifluoromethyldiazirine was studied by laser flash photolysis (LFP) to obtain the absolute kinetics of p-tolyl(trifluoromethyl)carbene 1. The absolute rate constants for the reactions of 1 with pyridine, ketones and quenchers of biological interest were obtained. The implications of the data for photoaffinity labeling experiments are discussed.
A. Admasu, A. D. Gudmundsdóttir, M. S. Platz, D. S. Watt, S. Kwiatkowski and P. J. Crocker, J. Chem. Soc., Perkin Trans. 2, 1998, 1093 DOI: 10.1039/A707586C
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