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Issue 5, 1998
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A laser flash photolysis study of p-tolyl(trifluoromethyl)carbene

Abstract

3-p-Tolyl-3-trifluoromethyldiazirine was studied by laser flash photolysis (LFP) to obtain the absolute kinetics of p-tolyl(trifluoromethyl)carbene 1. The absolute rate constants for the reactions of 1 with pyridine, ketones and quenchers of biological interest were obtained. The implications of the data for photoaffinity labeling experiments are discussed.

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Article information


J. Chem. Soc., Perkin Trans. 2, 1998, 1093-1100
Article type
Paper

A laser flash photolysis study of p-tolyl(trifluoromethyl)carbene

A. Admasu, A. D. Gudmundsdóttir, M. S. Platz, D. S. Watt, S. Kwiatkowski and P. J. Crocker, J. Chem. Soc., Perkin Trans. 2, 1998, 1093
DOI: 10.1039/A707586C

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