SCHEDULED MAINTENANCE
Saddle-shaped [7]circulene (1) is prepared by an extremely simple procedure that involves a 2,15-ethano-bridged hexahelicene intermediate. Reduction properties of the [7]circulene have been investigated by means of voltammetry and ESR spectroscopy and compared with those of planar [6]circulene (coronene) (2).
M. Sato, K. Yamamoto, H. Sonobe, K. Yano, H. Matsubara, H. Fujita, T. Sugimoto and K. Yamamoto, J. Chem. Soc., Perkin Trans. 2, 1998, 1909 DOI: 10.1039/A803306D
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