An asymmetric synthesis of homochiral α-amino acids has been developed which is based on the conjugate addition of organocuprates to the dehydroalanine equivalent (3S
)-N,N′-bis(p-methoxybenzyl)-3-isopropyl-6-methylenepiperazine-2,5-dione 6.
S. D. Bull, S. G. Davies and M. D. O'Shea, J. Chem. Soc., Perkin Trans. 1, 1998, 3657 DOI: 10.1039/A807618I
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