Issue 22, 1998

Easy access to various substituted 4-aminocyclopentenes by rearrangement of 2-ethenyl-substituted cyclopropylamines

Abstract

A variety of 2-ethenyl-substituted cyclopropylamines upon flash vacuum pyrolysis or under silver nitrate catalysis cleanly undergo ring enlargement and afford high yields (up to 95%) of 4-aminocyclopent-1-enes, some of which have unprecedented substitution patterns.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1998, 3699-3702

Easy access to various substituted 4-aminocyclopentenes by rearrangement of 2-ethenyl-substituted cyclopropylamines

C. M. Williams and A. de Meijere, J. Chem. Soc., Perkin Trans. 1, 1998, 3699 DOI: 10.1039/A807012A

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