Issue 20, 1998
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Flash vacuum pyrolysis of stabilised phosphorus ylides. Part 13.1 Extrusion of Ph3P from sulfinyl ylides and reactivity of the resulting sulfinyl carbenes

R. Alan Aitken,   Martin J. Drysdale  and  Bruce M. Ryan  

Abstract

Six α-sulfinyl phosphorus ylides 6 have been prepared and are found upon flash vacuum pyrolysis at 500 °C to undergo mainly extrusion of Ph3P to give thioesters, presumably by 1,2-oxygen transfer in the initially formed sulfinyl carbenes; for α-arylsulfinyl ylides loss of Ph3PO to give additional products is also observed.

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Article information

DOI
https://doi.org/10.1039/A806182C
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1998, 3345-3348

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Flash vacuum pyrolysis of stabilised phosphorus ylides. Part 13.1 Extrusion of Ph3P from sulfinyl ylides and reactivity of the resulting sulfinyl carbenes

R. Alan Aitken, M. J. Drysdale and B. M. Ryan, J. Chem. Soc., Perkin Trans. 1, 1998, 3345 DOI: 10.1039/A806182C

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