Three successive reactions of a dimethoxy arene with allylic cation equivalents were used to convert 2,3-dimethoxy-4-methyl-1-iodobenzene to the hexahydro-1H-phenalene system of the potent marine antiinflammatory pseudopterosins G–J.
J. LeBrazidec, P. J. Kocienski, J. D. Connolly and K. W. Muir, J. Chem. Soc., Perkin Trans. 1, 1998, 2475 DOI: 10.1039/A803888K
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