New pyrrolidine-based ene carbamates have been efficiently synthesized and the first example of asymmetric hydrogenation of this kind of substrate is reported, leading to the preparation of 2-arylmethylpyrrolidine precursors to benzoindolizinones in high yields and enantioselectivities up to 57%.
A. Couture, E. Deniau, S. Lebrun, P. Grandclaudon and J. Carpentier, J. Chem. Soc., Perkin Trans. 1, 1998, 1403 DOI: 10.1039/A709053F
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