An intramolecular Diels–Alder reaction for the construction of a lactone ring fused-tricyclic ring system has been developed using propionate as the dienophile. As an application of this reaction, an enantio- and diastereo-selective synthesis of a tetracyclic ring system of a myrocin analogue has been studied.
S. Yamada, S. Nagashima, Y. Takaoka, S. Torihara, M. Tanaka, H. Suemune and M. Aso, J. Chem. Soc., Perkin Trans. 1, 1998, 1269 DOI: 10.1039/A708497H
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