Mono- or di-carbamates of 1,1′-bi-2-naphthol ortholithiate with Bus
Li–TMEDA. The resulting anions may either be captured by MeI or allowed to undergo anionic Fries rearrangement. Thus generalised two-step routes to mono- and di-(3-alkyl) or -(3-amido) substituted 2,2′-binapthols is demonstrated.
M. R. Dennis and S. Woodward, J. Chem. Soc., Perkin Trans. 1, 1998, 1081 DOI: 10.1039/A708436F
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