The preparation and reaction of 3,3,3-trifluoropropiondithioacetals 5 as possible trifluoromethyl-containing synthons has been studied. The synthesis of alkyl 1-acetoxy-3,3,3-trifluoropropyl thioethers 6 from compounds 5 and the Lewis acid-mediated reactions of compounds 6 with enol silyl ethers are also described.
H. Guan, B. Luo, Q. Wang and C. Hu, J. Chem. Soc., Perkin Trans. 1, 1998, 279 DOI: 10.1039/A705602H
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