In order to determine the absolute stereochemistry of amphidinolide L 1, a cytotoxic macrolide from a marine dinoflagellate, (16R, 18S, 20R, 22S, 23R, and 25R)-2, one of the eight possible diastereoisomers of the C(15)–C(26) segment has been synthesized, thus providing an authentic sample for degradation studies of 1.
M. Tsuda, A. Hatakeyama and J. Kobayashi, J. Chem. Soc., Perkin Trans. 1, 1998, 149 DOI: 10.1039/A703141F
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