Self-assembly of a polynuclear ribbon: the structure of {[Cu2(CN)2(L)]·MeNO2}∞ [L=4,7-bis(2-cyanoethyl)- 1-thia-4,7-diazacyclononane]
Abstract
The compound {[Cu2(CN)2(L)]·MeNO2}∞ [L=4,7-bis(2-cyanoethyl)-1-thia-4,7-diazacyclononane] has been prepared by reaction of CuCN with L. The complex shows an unusual CuI–CN one-dimensional polymer capped by macrocyclic ligands.