Issue 10, 1998

Gold(I) complexes with amine ligands. 3 Competition between auriophilic and hydrogen bonding interactions in dimeric species

Abstract

The gold(I) complexes (pip)2Au+Cl- and (Cy2NH)AuCl (pip=piperidine, Cy=cyclohexyl) crystallise as loose dimers; in the ionic species N–H···Cl- hydrogen bonding is the main secondary interaction, whereas in the neutral complex the N–H···Cl hydrogen bonding is weaker but is compensated by an auriophilic interaction.

Article information

Article type
Paper

New J. Chem., 1998,22, 1041-1042

Gold(I) complexes with amine ligands. 3 Competition between auriophilic and hydrogen bonding interactions in dimeric species

P. G. Jones and B. Ahrens, New J. Chem., 1998, 22, 1041 DOI: 10.1039/A805587D

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