8-(Diethylborylmethylamino)-3-phenyl-1-azaazulene (5) has been synthesized, in which the 8-methylamino-azaazulene moiety is found to act as a bidentate ligand whose two boron–nitrogen bond lengths are almost equivalent.
Y. Sugihara, T. Murafuji, N. Abe, M. Takeda and A. Kakehi, New J. Chem., 1998, 22, 1031 DOI: 10.1039/A805547E
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