The equilibrium rates of dioxygen and carbon monoxide binding have been measured for a series of capped iron porphyrins called ‘arbor’. The affinity for dioxygen of these models is 100-fold higher than the highest previously reported values.
D. Ricard, B. Andrioletti, B. Boitrel and R. Guilard, New J. Chem., 1998, 22, 1331 DOI: 10.1039/A805357J
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