µ3-Phosphido cluster 2, which is readily accessible from the cobalt chelate 1 by treatment with tert-butylphosphaethyne, reacts with red selenium to give the moderately air- and light-sensitive tetraselenide 4 with µ3tert-butylcarbyn and µ3 PSe ligands in 48% yield. The crystal structure of 4 is reported and compared to those of closely related clusters.
J. Foerstner, R. Wartchow and H. Butenschön, New J. Chem., 1998, 22, 1155 DOI: 10.1039/A803784A
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
