Non-covalent synthesis was used in the controlled assembly of metallodendrimers containing up to 12 porphyrins on the surface. A porphyrin containing four Pd-Cl complexes was synthesized to assemble dendrimers with a porphyrin in the nucleus. 1H NMR, ES-MS and MALDI-TOF mass spectrometry were used to characterize the nanometer-size assemblies.
W. T. S. Huck, A. Rohrer, A. T. Anilkumar, R. H. Fokkens, N. M. M. Nibbering, F. C. J. M. van Veggel and D. N. Reinhoudt, New J. Chem., 1998, 22, 165 DOI: 10.1039/A708323H
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