The new phase NaBi3V2O10 is reported; it was synthesised by oxide reaction at 600 °C and is triclinic with a=7.2026(10), b=7.0600(9), c=5.5312(6) Å, α=84.542(12), β=113.318(11) and γ=112.267(12)°; it is an oxide ion conductor with conductivity of ca. 1.5 mS cm–1 at 675 °C.
D. C. Sinclair, C. J. Watson, R. Alan Howie, J. M. S. Skakle, A. M. Coats, C. A. Kirk, E. E. Lachowski and J. Marr, J. Mater. Chem., 1998, 8, 281 DOI: 10.1039/A707760B
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