Electrochemical oxidation of the solution containing benzo[c]phenothiazine (B[c]PT) and dicyanophthalocyaninatocobalt(iii) anion, [Co(Pc)(CN)2 ]– , gives crystalline solids containing cyano-bridged cobalt–phthalocyanine dimer units. The dimeric species which may exist in equilibrium with the monomer is selectively trapped by crystallization with the B[c]PT cation radical.
S. Takano, T. Naito and T. Inabe, J. Mater. Chem., 1998, 8, 511 DOI: 10.1039/A707540E
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