Efficient and Mild Oxidative Decarboxylation of Aryl-substituted Carboxylic Acids by Iron and Manganese Porphyrin Periodate Systems
Abstract
The oxidative decarboxylation of α-aryl carboxylic acids to the corresponding carbonyl derivatives was observed in catalytic systems containing tetrabutylammonium periodate and metallotetraphenylporphyrins (metal=FeIII or MnIII) at room temperature.
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