Regioselective homolytic alkylations leading to substitution for highly electron-deficient aromatics such as fluoro- or trifluoromethyl-substituted benzaldehydes and benzonitriles are observed via electron transfer chain processes in the presence of 1,4-diazabicyclo[2.2.2]octane.
B. Hyo Kim, Y. Seok Lee, D. Byung Lee, I. Jeon, Y. Moo Jun, W. Baik and G. A. Russell, J. Chem. Res. (S), 1998, 826 DOI: 10.1039/A805297B
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