The reactions of chiral alkoxy- and aminomethyl-substituted α-silylallyl carbanions with aldehydes gave 1-silyl-homoallylic alcohols with high γ-regioselection and E-stereoselection, as well as a diastereomeric excess of 8–69%, depending on the chiral substituents on silicon, the aldehydes and the base used.
L. Liu and D. Wang, J. Chem. Res. (S), 1998, 612 DOI: 10.1039/A802886I
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