Issue 9, 1998

Vinyltriphenylphosphonium Salt Mediated One-pot Synthesis of Dialkyl 5-formyl-2H-pyran-2,3-dicarboxylate

Abstract

Protonation of the highly reactive 1:1 intermediates produced in the reaction between triphenylphosphine and dialkyl acetylenedicarboxylates by triformylmethane leads to vinyltriphenylphosphonium salts which undergo an intramolecular Wittig reaction to produce dialkyl 5-formyl-2H-pyran-2,3-dicarboxylates in fairly high yields.

Article information

Article type
Paper

J. Chem. Res. (S), 1998, 584-585

Vinyltriphenylphosphonium Salt Mediated One-pot Synthesis of Dialkyl 5-formyl-2H-pyran-2,3-dicarboxylate

A. Shaabani and F. Sadeghi Nejat, J. Chem. Res. (S), 1998, 584 DOI: 10.1039/A802444H

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