A synthesis of isocryptolepine 2 is described the key steps in which are (a) palladium(0) coupling to an indol-2-ylstannane and (b) an intramolecular Vilsmeier reaction to construct the 3-aminoalkylidene-3H-indole unit of the alkaloid.
P. E. Murray, K. Mills and J. A. Joule, J. Chem. Res. (S), 1998, 377 DOI: 10.1039/A801313F
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