Issue 9, 1998

Dimolybdenum Complexes with a Potentially Tetradentate PNNP Ligand,2,7-Bis(diphenylphosphino)-1,8-naphthyridine (dpnapy)

Abstract

Reaction of cis-[Mo2(O2CCH3)2(CH3CN)6](BF4)2 with a potentially tetradentate PNNP ligand, 2,7-bis(diphenylphosphino)-1,8-naphthyridine (dpnapy), in a 1:2 molar ratio afforded a mixture of isomeric dimolybdenum complexes, cis-[Mo2(O2CCH3)2(dpnapy-N,P)2](BF4)2 (1) and trans-[Mo2(O2CCH3)2(dpnapy-N,N′)2](BF4)2 (2) in 63 and 5% yields, respectively, which were characterized by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Res. (S), 1998, 538-539

Dimolybdenum Complexes with a Potentially Tetradentate PNNP Ligand,2,7-Bis(diphenylphosphino)-1,8-naphthyridine (dpnapy)

T. Tanase, T. Igoshi, K. Kobayashi and Y. Yamamoto, J. Chem. Res. (S), 1998, 538 DOI: 10.1039/A800308D

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