Deuterium labeling experiments and molecular orbital (MNDO) calculations indicate that 1,6-homolytic hydrogen transfer from C8 to C3 is not responsible for the products observed when diethylene glycol bis(allyl carbonate) is treated with tert-butoxyl radicals in the presence of 1′,1′,3′,3′-tetramethylisoindolinyl-2′-oxyl.
A. Qureshi and C. H. Schiesser, J. Chem. Res. (S), 1998, 328 DOI: 10.1039/A707048I
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