The open-shell complexes, (PhCNEEN)Pt(dppe) (E = S or Se) decompose via a chalcogen abstraction process coupled with N-protonation to yield the novel 10π metalla-heterocyclic cations {[PhCN(H)N(H)E]Pt(dppe)}+: the selenium complex is characterised by X-ray crystallography as its chloride salt.
N. Feeder, R. J. Less, J. M. Rawson and J. Nicholas B. Smith, J. Chem. Soc., Dalton Trans., 1998, 4091 DOI: 10.1039/A808758J
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