The reaction between (Me3C)2MeSiNHLi and SiCl4 afforded R–NH–SiCl3 1, and (R–NH)2SiCl2 2; 1 reacted with BuLi with formation of the tetrachlorocyclodisilazane (RN–SiCl2)2 3, R = SiMe(CMe3)2, hydrogenation of which with LiAlH4 resulted in the first cyclodisilazane (RN–SiH2)2 4.
B. Jaschke, R. Herbst-Irmer, U. Klingebiel, P. Neugebauer and T. Pape, J. Chem. Soc., Dalton Trans., 1998, 2953 DOI: 10.1039/A806267F
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