Novel charge transfer complexes based on MCp2 (M = Co or Ni) and dicyanodihydrofullerene [C60(CN)2] have been prepared and the charge transfer in them investigated by UV-NIR, EPR and other spectra. The dicyanodihydrofullerene was reduced to the monoanion in the compound CoCp2·C60(CN)2·CS2, which showed a characteristic NIR band at 1016 nm.
Z. Suo, X. Wei, K. Zhou, Y. Zhang, C. Li and Z. Xu, J. Chem. Soc., Dalton Trans., 1998, 3875 DOI: 10.1039/A803911I
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