Issue 14, 1998
From the journal:

Journal of the Chemical Society, Dalton Transactions

Bis[dirhodium(II)] complexes with a Rh4(µ-Cl)4 core: preparation and characterization ‡

Zhiyong Yang,   Hiroki Oki,   Masahiro Ebihara  and  Takashi Kawamura  

Abstract

The reaction of [Rh2(O2CPrn)4] or [Rh2(mhp)4] (Hmhp = 2-hydroxy-6-methylpyridine) with a trialkylchlorosilane followed by crystallization from a nitrile unexpectedly gave [Rh4(O2CPrn)4Cl4(CH3CN)4] 1 or an isomer of [Rh4(mhp)4Cl4(PhCN)2] both with a ‘twisted-cage’ Rh4(µ-Cl)4 core, which were studied by X-ray crystallography, cyclic voltammetry and UV/VIS spectroscopy; 1 catalyzed the hydrogenation of acrylic acid in water.

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Article information

DOI
https://doi.org/10.1039/A803623C
Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 2277-2278

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Bis[dirhodium(II)] complexes with a Rh4(µ-Cl)4 core: preparation and characterization ‡

Z. Yang, H. Oki, M. Ebihara and T. Kawamura, J. Chem. Soc., Dalton Trans., 1998, 2277 DOI: 10.1039/A803623C

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