Issue 19, 1998
From the journal:

Journal of the Chemical Society, Dalton Transactions

Vibrational and crystallographic studies of dioxohalogenomolybdenum(VI) complexes with crown ethers

Michael J. Taylor,   Clifton E. F. Rickard  and  Lars A. Kloo  

Abstract

Crown ether adducts [MoO2X2(H2O)2]·2H2O·18-crown-6 (X = Br 1 or Cl 2), obtained by combining solutions of MoVI in HBr or HCl with 1,4,7,10,13,16-hexaoxacyclooctadecane (18-crown-6), were shown by X-ray crystallography to contain MoO2X2(H2O)2 units with cis,trans,cis ligand arrangement. Recrystallisation from methyl alcohol yielded [MoO2Cl2(MeOH)2]·18-crown-6 3 which was also characterised by X-ray analysis. Adding potassium ions to the HCl system gave [K(18-crown-6)][MoO2Cl3(H2O)] 4 which was identified by studying Raman and IR spectra of the series.

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Article information

DOI
https://doi.org/10.1039/A803295E
Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 3195-3198

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Vibrational and crystallographic studies of dioxohalogenomolybdenum(VI) complexes with crown ethers

M. J. Taylor, C. E. F. Rickard and L. A. Kloo, J. Chem. Soc., Dalton Trans., 1998, 3195 DOI: 10.1039/A803295E

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