Reaction of a MnII thiolate complex bearing hydrotris(3,5-diisopropylpyrazol-1-yl)borate with O2 resulted in O–O bond activation to give a dinuclear MnIII bis(µ-oxo) complex and a ligand-oxygenated dinuclear MnIII µ-oxo complex, or the dinuclear MnIII,IV µ-acetato-bis(µ-oxo) complex in the presence of a MnII acetate complex.
H. Komatsuzaki, Y. Nagasu, K. Suzuki, T. Shibasaki, M. Satoh, F. Ebina, S. Hikichi, M. Akita and Y. Moro-oka, J. Chem. Soc., Dalton Trans., 1998, 511 DOI: 10.1039/A708210J
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