Issue 24, 1998

Synthesis of 2-deoxy and 2,6-dideoxy glycosides under neutral conditions in LiClO4/Et2O mixtures

Abstract

Glycosides of 2-deoxy and 2,6-dideoxy carbohydrates were built up in high yields and with high stereoselectivity in 0.1 M LiClO4/Et2O mixtures; the glycosidations proceed under neutral conditions and without need for an additional promoter such as a strong Lewis acid, a heavy metal salt or an alkylating reagent.

Article information

Article type
Paper

Chem. Commun., 1998, 2759-2769

Synthesis of 2-deoxy and 2,6-dideoxy glycosides under neutral conditions in LiClO4/Et2O mixtures

H. Schene and H. Waldmann, Chem. Commun., 1998, 2759 DOI: 10.1039/A807734G

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