A series of chiral thioether dervatives of ferrocenyl-oxazolines, prepared with diastereoselectivities >95:5, have been shown to be highly efficient catalysts for a palladium catalyzed allylic substitution reaction, with enantioselectivity of 81–98% ee, and the role of planar chirality in these ligands was also discussed.
S. You, Y. Zhou, X. Hou and L. Dai, Chem. Commun., 1998, 2765 DOI: 10.1039/A808267G
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